@misc{10481/82918,
year = {2023},
month = {6},
url = {https://hdl.handle.net/10481/82918},
abstract = {Metal–organic frameworks (MOFs) based on high-connected nets
are generally very attractive due to their combined robustness
and porosity. Here, we describe the synthesis of BCN-348, a new
high-connected Zr-MOF built from an 8-connected (8-c) cubic Zroxocluster
and an 8-c organic linker. BCN-348 contains a minimal
edge-transitive 3,4,8-c eps net, and combines mesoporosity with
thermal and hydrolytic stability. Encouraging results from preliminary
studies on its use as a catalyst for hydrolysis of a nerve-agent
simulant suggest its potential as an agent for detoxification of
chemical weapons and other pernicious compounds.},
organization = {European Union’s
Horizon 2020 research and innovation programme, under
grant agreement No 101019003},
organization = {Catalan AGAUR (project
2021 SGR 00458)},
organization = {the CERCA Programme/Generalitat de Catalunya,
and the Spanish MCIN/AEI/10.13039/501100011033 (Project
PID2020-113608RB-I00},
organization = {ICN2 is supported by the Severo
Ochoa Centres of Excellence programme},
organization = {Grant CEX2021-
001214-S, funded by MCIN/AEI/10.13039.501100011033},
publisher = {Royal Society of Chemstry},
title = {A mesoporous Zr-based metal–organic framework driven by the assembly of an octatopic linker},
doi = {10.1039/d3cc01831h},
author = {Ortín Rubio, Borja and Carmona Fernández, Francisco Jesús},
}