@misc{10481/78975,
year = {2022},
month = {11},
url = {https://hdl.handle.net/10481/78975},
abstract = {A new family of metal−organic frameworks (MOFs)
named GR-MOFs with the chemical formula {[Mx(BCA)y]-
(H2O)z(DMF)w} (x,y,z,w: 1,1,2,0; 1,1.5,0,1; 1,2,2,1; and 1,1,0,2
for GR-MOF-11 to 14, respectively) based on s-block [M: Sr (GRMOF-
11), Ba (GR-MOF-14)] and d-block [M: Y (GR-MOF-12)
and Cd (GR-MOF-13)] metals together with the biquinoline
ligand 2,2′-bicinchoninic acid (H2BCA) has been synthetized by a
solvothermal route and fully characterized by elemental and
thermogravimetric analysis, Fourier transform infrared spectroscopy,
photoluminescence, particle size distribution through optical
microscopy, electrophoretic mobility, and finally, X-ray singlecrystal
and powder diffraction. The structural characterization
reveals that these 2D and 3D MOFs possess a rich variety of
coordination modes that maintained the Janus-head topology on the ligand in most of the cases. The new MOFs were studied in the
catalyzed cyanosilylation and hydroboration of an extensive group of aldehydes and ketones, wherein the s-block metal-based MOFs
GR-MOF-11 and GR-MOF-14 provided the highest efficiency ever reported in the MOF-catalyzed cyanosilylation of carbonyl
compounds by using only 0.5 mol % of catalyst loading, room temperature, and solvent-free conditions. Furthermore, the
hydroboration of ketones has been reported for the first time with this type of s-block metal catalysts obtaining from moderate to
good conversions.},
organization = {MCIN/AEI	CTQ2017-84334 R	
PGC2018-102052 B-C21	
PGC2018-102052 A-C22},
organization = {ERDF A way of making Europe},
organization = {Junta de Andalucia	102C2000004	
CV20-78799	
P20_01041},
organization = {UAL-FEDER UAL2020-AGR-B1781},
organization = {FEDER 2014-2020 A-RNM-433-UGR18},
organization = {ProyExcel_00386	
ProyExcel_00105},
organization = {B-FQM-734-UGR20	
FQM-376	
FQM-394},
organization = {Basque Government	IT1755-22	
IT1500-22},
organization = {Gobierno de Espana MCIN/AEI	PDC2021-121248-I00	
PLEC2021-007774},
organization = {Juan de la Cierva Incorporacion Fellowship	IJC2019-038894-I},
organization = {Hipatia fellowship (University of Almeria)},
organization = {Universidad de Granada/CBUA},
publisher = {American Chemical Society},
title = {Metal−Organic Frameworks Based on a Janus-Head Biquinoline Ligand as Catalysts in the Transformation of Carbonyl Compounds into Cyanohydrins and Alcohols},
doi = {10.1021/acs.cgd.2c00985},
author = {Pérez, Juana M. and Morales Cámara, Samuel and Ruiz Cuevas, Noelia and Choquesillo Lazarte, Duane and Abdelkader Fernández, Víctor Karim and Rodríguez Diéguez, Antonio and Rojas Macías, Sara},
}