@misc{10481/76203,
year = {2022},
url = {http://hdl.handle.net/10481/76203},
abstract = {The crystal structure of the anionic zinc–[amino­(iminio)meth­yl]phospho­nate one-dimensional coordination polymer, Zn-AIMP, is reported; the negative charge is balanced by an oxidanium cation (H3O+) to give the composition {(H3O)[Zn(CH4N2PO3)3]}n. The building unit of the coordination polymer comprises a divalent Zn2+ cation (site symmetry \overline3..) and three [amino(iminio)meth­yl]phospho­nate mono-anionic ligands (point group symmetry m). The AIMP ligand exists in a zwitterionic form with a total charge −1 as the phospho­nate is fully deprotonated (–PO32−), while the amino­(iminio)methyl moiety is protonated (H2N—C—NH2+).},
organization = {Research project
‘Innovative Materials and Applications’ (INNOVAMAT, KA
10694) by the Special Account for Research Grants},
publisher = {International Union of Crystallography},
keywords = {Phosphonate},
keywords = {Coordination polymers},
keywords = {Zinc},
keywords = {One-dimensional network},
keywords = {Crystal structure},
title = {catena-Poly[oxidanium [tris{μ-[amino(iminio)methyl]phosphonato}zincate(II)]]},
doi = {10.1107/S2414314622002474},
author = {Chachlaki, Elpiniki and Choquesillo Lazarte, Duane and Demadis, Konstantinos D.},
}