@misc{10481/72809,
year = {2022},
month = {1},
url = {http://hdl.handle.net/10481/72809},
abstract = {On-surface synthesis, complementary to wet chemistry, has been demonstrated to be a
valid approach for the synthesis of tailored graphenic nanostructures with atomic precision. Among
the different existing strategies used to tune the optoelectronic and magnetic properties of these
nanostructures, the introduction of non-hexagonal rings inducing out-of-plane distortions is a promising pathway that has been scarcely explored on surfaces. Here, we demonstrate that non-hexagonal
rings, in the form of tropone (cycloheptatrienone) moieties, are thermally transformed into phenyl or
cyclopentadienone moieties upon an unprecedented surface-mediated retro–Buchner-type reaction
involving a decarbonylation or an intramolecular rearrangement of the CO unit, respectively.},
organization = {Junta de Andalucía-Consejería de Economía y Conocimiento

B-FQM-428-UGR20, BES-2015-072642, RYC2018-024364-I},
organization = {MCIN},
organization = {Ministerio de Universidades

FPU18/05938},
organization = {European Commission

FOTOART-CM S2018/NMT-4367},
organization = {European Research Council},
organization = {Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung  200020-182015},
organization = {European Social Fund},
organization = {Universidad de Granada},
organization = {European Regional Development Fund

011033, PID2020-113142RB-C21, S2018/NMT-4367},
organization = {National Center of Competence in Research Materials’ Revolution: Computational Design and Discovery of Novel Materials

51NF40-182892},
organization = {Agencia Estatal de Investigación},
publisher = {MDPI},
keywords = {On-surface synthesis},
keywords = {Graphene nanoribbons},
keywords = {Retro-Buchner reaction},
keywords = {Intramolecular rearrangement},
keywords = {Scanning tunneling microscope},
keywords = {Non-contact atomic force microscope},
keywords = {CO functionalized tip},
keywords = {X-ray photoelectron spectroscopy},
title = {On-Surface Thermal Stability of a Graphenic Structure Incorporating a Tropone Moiety},
doi = {10.3390/nano12030488},
author = {Rodríguez Márquez, Irene and Villalobos Romero, Federico and Cuerva Carvajal, Juan Manuel and González Campaña, Araceli},
}