@misc{10481/71775,
year = {2021},
month = {11},
url = {http://hdl.handle.net/10481/71775},
abstract = {The synthesis of two biocatalysts based on a commercial Candida antarctica lipase B, CALB enzyme (E), physically immobilized on two silica supports, was carried out. The first support was a periodic mesoporous organosilica (PMO) and the second one was a commercial silica modified with octyl groups (octyl-MS3030). The maximum enzyme load was 122 mg enzyme/g support on PMO and 288 mg enzyme/g support on octyl-MS3030. In addition, the biocatalytic efficiency was corroborated by two reaction tests based on the hydrolysis of p-nitrophenylacetate (p-NPA) and tributyrin (TB). The transesterification of sunflower oil with ethanol was carried out over the bio-catalysts synthesized at the following reaction conditions: 6 mL sunflower oil, 1.75 mL EtOH, 30 °C, 25 μL NaOH 10 N and 300 rpm, attaining conversion values over 80% after 3 h of reaction time. According to the results obtained, we can confirm that these biocatalytic systems are viable candi-dates to develop, optimize and improve a new methodology to achieve the integration of glycerol in different monoacylglycerol molecules together with fatty acid ethyl esters (FAEE) molecules to obtain Ecodiesel.},
organization = {Consejería de Transformación Económica, Industria, Conocimiento y Universidades de la Junta de Andalucía},
organization = {MICIIN

PID2019-104953RB-100},
organization = {MINECO-ENE2016-81013-R},
organization = {UCO-FEDER

1264113-R, GOIPD/2015/287, P18-RT-4822},
organization = {European Commission},
organization = {European Regional Development Fund},
organization = {Agencia Estatal de Investigación},
publisher = {MDPI},
keywords = {Biofuel},
keywords = {Ecodiesel},
keywords = {Biodiésel},
keywords = {Commercial CALB lipase},
keywords = {Ordered mesoporous materials (PMO)},
keywords = {Amorphous siliceous material MS3030},
title = {Enzymatic Production of Ecodiesel by Using a Commercial Lipase CALB, Immobilized by Physical Adsorption on Mesoporous Organosilica Materials.},
doi = {10.3390/catal11111350},
author = {Luna, Diego and Verdugo-Escamilla, Cristóbal},
}