@misc{10481/69992,
year = {2021},
url = {http://hdl.handle.net/10481/69992},
abstract = {The effect of acidic hydrolysis duration on nanocellulose size, morphology, and proper ties
was investigated, which opens up a whole new horizon of versatility in poplar applications. This
study aimed to examine Spanish poplar wastes as raw material to extract crystalline nanocellulose
(CNC), which substantiates the importance of poplar wastes. Wastes were pulped using 1 L of
10% NaOH (wt./wt.) solution, and bleached several times by NaClO2
; afterwards, white wastes
were subjected to acidic hydrolysis by 60% H2SO4
for either 5, 10, or 15 min. Microcrystalline
cellulose (MCC) underwent a similar hydrolysis protocol as poplar as control. TEM, IR, and XRD
characterization techniques were performed. Poplar based nanocellulose sized 219 nm length and
69 nm width after 15 min acidic hydrolysis. MCC yielded 122 nm length and 12 nm width crystals
after 10 min acidic hydrolysis. Hydrolysis resulted in a drastic change and intense peaks at 3500 and
2900 cm−1
for nanocellulose. Although pre-hydrolysis fiber treatment was not influencial on the
crystallinity of poplar, acidic hydrolysis remarkably raised the crystallinity index (CI) by 7–8%. The
more hydrolysis duration was prolonged, the size of the resulting crystal (whisker) decreased, and
the aspect ratio increased. Hydrolysis was more impactful on MCC than poplar. However, for future
work, it seems that longer duration of pulping and bleaching could have significantly removed
unwanted components (hemicellulose and lignin), showcased in IR and XRD, and hence smoothened
the following hydrolysis.},
organization = {European Union under umbrella of Erasmus+ KA107 PhD
Mobility scheme},
publisher = {MDPI},
keywords = {Bioresources},
keywords = {Biomaterials},
keywords = {Nanocellulose},
keywords = {Residues},
keywords = {Valorization},
keywords = {Acidic hydrolysis},
title = {Spanish Poplar Biomass as a Precursor for Nanocellulose Extraction},
doi = {10.3390/app11156863},
author = {Mehanny, Sherif and Gil-San Millán, Rodrigo},
}