@misc{10481/33166,
year = {2010},
url = {http://hdl.handle.net/10481/33166},
abstract = {The two independent MnII ions in the polymeric title compound, {[Mn2(C6H2N2O4)(C10H8N2)(H2O)6]SO4·3H2O}, exhibit distorted MnN2O4 octahedral coordination geometries, with the pyrimidine-4,6-dicarboxylate (pmdc) ligand acting in the bis-chelating [mu]-([kappa]O,[kappa]N:[kappa]O',[kappa]N') bridging mode and the 4,4'-bipyridine (bpy) ligand in the [mu]-([kappa]N:[kappa]N') bridging mode. The remaining coordination sites are occupied by O atoms of water molecules. As a consequence, cationic chains of [Mn2([mu]-pmdc)([mu]-4,4'-bpy)(H2O)6]2+ are generated, which extend approximately along the a axis. Sulfate counter-anions and three uncoordinated water molecules complete the structure, which is stabilized by multiple O-H...O hydrogen-bonding interactions between the structural units.},
organization = {Financial support from Spanish MEC (CTQ2008–00037/PPQ and SB-2005–0115) is gratefully acknowledged. The authors thank Professor Jorge A. R. Navarro and Miguel
Quiro´ s (U. Granada), Professor Oscar Castillo (U. Vasque Country) and Professor Norberto Masciocchi (U. Insubria) for
helpful discussions.},
publisher = {International Union of Crystallography},
keywords = {Crystal},
keywords = {Single-crystal X-ray study},
title = {catena-Poly[[[triaquamanganese(II)]-[mu]-4,4'-bipyridine-[kappa]2N:N'-[triaquamanganese(II)]-[mu]-pyrimidine-4,6-dicarboxylato-[kappa]4N1,O6:N3,O4] sulfate trihydrate]},
doi = {10.1107/S1600536809053896},
author = {Wang, Wenguo and Barea Martínez, Elisa María and Linares Ordóñez, Fátima},
}