@misc{10481/111009, year = {2017}, month = {6}, url = {https://hdl.handle.net/10481/111009}, abstract = {Copper-ion-exchanged nickel pyrazolate frameworks behave as selective heterogeneous catalysts for the one-pot, two-step (Henry reaction/Michael type addition) synthesis of neuroactive pharmaceutical intermediates starting from nitromethane and benzaldehyde. Tuning the basicity of multifunctional metal–organic framework catalysts through ion exchange with copper(- II) cations allows the tandem C@C bond-forming process to be selectively directed towards the desired pharmaceutical intermediate.}, organization = {Universidad de Granada (Dpto de Química Inorgánica)}, organization = {Spanish Ministry of Economy and Competitiveness (CTQ2014-53486-R)}, organization = {Fonds Wetenschappelijk Onderzoek (G.0256.14N)}, organization = {Horizon 2020, Marie Sklodowska–Curie (750391, project acronym SINMOF)}, publisher = {Wiley}, keywords = {Tunable basicity}, keywords = {C-C bond formation}, keywords = {Heterogeneous catalysis}, title = {Selective One-Pot Two-Step C-C Bond Formation using Metal–Organic Frameworks with Mild Basicity as Heterogeneous Catalysts}, doi = {10.1002/cctc.201700784}, author = {Cirujano, Francisco G. and López-Maya, Elena and Rodríguez-Albelo, Luisa Marleny and Barea Martínez, Elisa María and Rodríguez Navarro, Jorge Andrés and De Vos, Dirk E}, }