@misc{10481/110999,
year = {2015},
month = {5},
url = {https://hdl.handle.net/10481/110999},
abstract = {The current technology of air-filtration materials for protection against highly toxic chemicals, that is, chemical-warfare
agents, is mainly based on the broad and effective adsorptive properties of hydrophobic activated carbons. However, adsorption does not prevent these materials from behaving as secondary emitters once they are contaminated. Thus, the development of efficient self-cleaning filters is of high interest.
Herein, we report how we can take advantage of the improved phosphotriesterase catalytic activity of lithium alkoxide doped
zirconium(IV) metal–organic framework (MOF) materials to develop advanced self-detoxifying adsorbents of chemicalwarfare agents containing hydrolysable P-F, P-O, and C-Cl bonds. Moreover, we also show that it is possible to integrate these materials onto textiles, thereby combining air-permeation properties of the textiles with the self-detoxifying properties of the MOF material.},
organization = {Spanish Ministry of Defense (COINCIDENTE)},
organization = {Spanish Ministry of Economy (CTQ2011-22787/ PPQ, CTQ2014-53486-R)},
organization = {Marie Curie-IIF (LMRA)},
organization = {Junta de Andalucia (P09-FQM-4981)},
organization = {ERDF Operative Program of the Region of Murcia 2007–2013 (AALP)},
organization = {Universidad de Granada (Dpto de Química Inorgánica)},
publisher = {Wiley},
keywords = {Heterogeneous catalysis},
keywords = {Nerve agents},
keywords = {Hydrolysis},
title = {Textile/Metal–Organic-Framework Composites as Self-Detoxifying Filters for Chemical-Warfare Agents},
doi = {10.1002/anie.201502094},
author = {López Maya, Elena and Montoro, Carmen and Rodríguez-Albelo, Luisa Marleny and Aznar Cervantes, Salvador D. and Lozano-Pérez, Antonio Abel and Cenis, Jose Luis and Barea Martínez, Elisa María and Rodríguez Navarro, Jorge Andrés},
}