@misc{10481/108191, year = {2025}, month = {11}, url = {https://hdl.handle.net/10481/108191}, abstract = {Post-synthetic incorporation of amino acids into the Zr-based metal–organic framework DUT-67 via relatively green methods yields materials with enhanced CO2 affinity. Structural and sorption studies reveal high affinity for DUT-67-Trp, exploiting its dual functionality to achieve an adsorption enthalpy level comparable to those of high-performing frameworks. The findings provide a promising pathway towards developing sustainable amino-functionalized CO2 sorbents.}, organization = {European Union's Horizon 2020 - (101034324)}, organization = {MICIU/AEI/10.13039/501100011033 and the NextGenerationEU/PRTR - grants (PID2021-123839OB-I00) (PID2023-147972OB-I00) (RYC2018-024328-I) and (CNS2022-135261)}, organization = {Spanish Ministry of Science and Innovation - (CEX2018-000805-M) (CEX2023-001316-M)}, publisher = {Royal Society of Chemistry}, title = {Enhanced CO2 affinity in a metal–organic framework through green incorporation of a dual-functional amino acid}, doi = {10.1039/d5nr03069b}, author = {Loukopoulos, Edward and Barragán Soto, Sofía and Marugán Benito, Sergio and Borrego-Marin, Emilio and Rodríguez Navarro, Jorge Andrés and Platero-Prats, Ana E.}, }