@misc{10481/76387, year = {2022}, month = {6}, url = {http://hdl.handle.net/10481/76387}, abstract = {Essential oils have a vast number of applications in different areas of our daily life. Detailed chiral analysis and structural characterization of their constituents remains an important subject in analytical chemistry. Here, we report on a broadband rotational spectroscopy study of peppermint oil in the frequency range 2–8 GHz. We focus on an unambiguous determination of the excess enantiomers of the oil constituents menthone and isomenthone in the oil by applying chiralitysensitive rotational spectroscopy, the so-called microwave three-wave mixing (M3WM) technique. Additionally, a new menthol conformer, not previously characterized, was experimentally observed, and the gas-phase structures of the two conformers of menthol and menthone were determined experimentally based on the assignment of their 13C-isotopologues in natural abundance.}, organization = {German Research Foundation (DFG) 328961117 SFB 1319 ELCH}, organization = {Fundacion Alfonso Martin Escudero}, organization = {Ministerio de Ciencia, Innovacion y Universidades - MCIN/AEI FJC2018-035709-I}, publisher = {MDPI}, keywords = {Peppermint oil}, keywords = {Microwave spectroscopy}, keywords = {Substitution structure}, keywords = {Microwave three-wave mixing}, keywords = {Structural analysis}, title = {A Scent of Peppermint—A Microwave Spectroscopy Analysis on the Composition of Peppermint Oil}, doi = {10.3390/sym14061262}, author = {Krin, Anna and Quesada Moreno, María del Mar}, }