@misc{10481/74122,
year = {2022},
month = {3},
url = {http://hdl.handle.net/10481/74122},
abstract = {Herein, to the best of our knowledge, the first heterobimetallic Y/Eu porous metal–organic framework (MOF), based on 3-amino-4-hydroxybenzoic acid (H2L) ligand, with the following formulae {[Y3.5Eu1.5L6(OH)3(H2O)3]·12DMF}n (in advance, namely Y/Eu-MOF), is described. The three-dimensional structure has been synthesized by solvothermal routes and thoroughly characterized, by means of single crystal X-ray diffraction, powder X-ray diffraction, electronic microscopy, ICP-AES, electrophoretic mobility, and FTIR spectra. Intriguingly, the porous nature allows for coordinated solvent molecules displacement, yielding unsaturated metal centers, which can act as a Lewis acid catalyst. This novel supramolecular entity has been tested in cyanosilylation and hydroboration reactions on carbonyl substrates of a diverse nature, exhibiting an extraordinary activity.},
organization = {Cierva Incorporación IJC2019-038894-I},
organization = {State Research Agency
	CTQ2017-84334-R, PGC2018-102052-B-C21},
organization = {University of Almeria
	HIPATIA2021_04},
organization = {Ministerio de Ciencia, Innovación y Universidades},
organization = {European Commission},
organization = {European Regional Development Fund},
organization = {Junta de Andalucía

B-FQM-734-UGR20, FQM-394, IJC2019-038894-I, P20_01041, UAL2020-AGR-B1781},
publisher = {MDPI},
keywords = {Heterobimetallic},
keywords = {Metal-organic Frameworks (MOFs)},
keywords = {Cyanosilylation},
keywords = {Hydroboration},
keywords = {Yttrium},
keywords = {Europium},
title = {A Mixed Heterobimetallic Y/Eu-MOF for the Cyanosilylation and Hydroboration of Carbonyls},
doi = {10.3390/catal12030299},
author = {Echenique-Errandonea, Estitxu and López-Vargas, Mireya E. and Pérez, Juana M. and Rojas Macías, Sara and Choquesillo Lazarte, Duane and Seco, José M. and Fernández, Ignacio and Rodríguez Diéguez, Antonio},
}