Oil and gas production from the pyrolytic transformation of recycled plastic waste: An integral study by polymer families Calero De Hoces, Francisca Mónica Rodríguez Solís, Rafael Muñoz Batista, Mario Jesús Pérez Muñoz, Antonio Blázquez García, Gabriel Martín Lara, María Ángeles Municipal solid waste Plastic waste Pyrolysis Polymer families Supplementary data to this article can be found online at https://doi.org/10.1016/j.ces.2023.118569. Acknowledgments This work has received funding from project P20_00167 (FEDER/Junta de Andalucía-Consejería de Transformación Económica,Industria, Conocimiento y Universidades) and project B-RNM-78-UGR20 (FEDER/Junta de Andalucía-Consejería de Trans- formación Económica,Industria, Conocimiento y Universidades). Also, the authors are grateful for the supporting analyses provided by the external service of the University of Granada (CIC). Funding for open access charge: Universidad de Granada / CBUA. Different plastics recovered from a local urban solid waste plant were collected before landfilling, separated, and classified by families, i.e. polyethylene (PE), polypropylene (PP), high impact and expanded polystyrene (HIPS and EPS, respectively), polyethylene terephthalate (PET), and polyvinyl chloride (PVC). A systematic pyrolysis study was carried out to compare the different behavior registered in each plastic type, and an integral analysis of the produced oils and synthetic gas was conducted. In general terms, the oil yield followed the order EPS > PP > PE > HIPS > PET > PVC, reaching maximum values over 500 C after 1 h of treatment. The oil from HIPS, EPS, PET, and PP was rich in light compounds, i.e., C5-C9 hydrocarbons. Almost 100 % of the oil from HIPS and EPS pyrolysis was aromatic. The aromatic fraction was important in the case of PVC (57 %) and PET (45 %). PE produced an oil with the most varied distribution of compounds but rich in olefins (67 %). The analysis of the non-condensable composition of the gas showed that in all the pyrolysis gases methane was over 50 % (vol.), followed by ethane in importance. CO was produced in the case of PET. 2023-02-22T10:14:52Z 2023-02-22T10:14:52Z 2023-02-14 info:eu-repo/semantics/article Mónica Calero, R.R. Solís, M.J. Muñoz-Batista et al. Oil and gas production from the pyrolytic transformation of recycled plastic waste: An integral study by polymer families. Chemical Engineering Science 271 (2023) 118569 [https://doi.org/10.1016/j.ces.2023.118569] https://hdl.handle.net/10481/80141 https://doi.org/10.1016/j.ces.2023.118569 eng http://creativecommons.org/licenses/by-nc-nd/4.0/ info:eu-repo/semantics/openAccess Attribution-NonCommercial-NoDerivatives 4.0 Internacional Elsevier