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dc.contributor.authorRipoll, Consuelo
dc.contributor.authorCheng, Cheng
dc.contributor.authorGarcía-Fernández, Emilio
dc.contributor.authorLi, Jin
dc.contributor.authorOrte, Angel
dc.contributor.authorDo, Hainam
dc.contributor.authorJiao, Lijuan
dc.contributor.authorRobinson, David
dc.contributor.authorCrovetto, Luis
dc.contributor.authorGonzalez-Vera, Juan A.
dc.contributor.authorTalavera Rodríguez, Eva María 
dc.contributor.authorAlvarez-Pez, Jose M.
dc.contributor.authorBoens, Noël
dc.contributor.authorRuedas-Rama, Maria J.
dc.date.accessioned2019-03-11T07:07:31Z
dc.date.available2019-03-11T07:07:31Z
dc.date.issued2018
dc.identifier.citationRipoll, Consuelo... [et al.]. Synthesis and spectroscopy of benzylamine-substituted BODIPYs for bioimaging. Eur. J. Org. Chem. 2018, 2561–2571es_ES
dc.identifier.urihttps://doi.org/10.1002/ejoc.201800083
dc.identifier.urihttp://hdl.handle.net/10481/54913
dc.descriptionThis is the peer reviewed version of the following article: Eur. J. Org. Chem. 2018, 2561–2571, which has been published in final form at https://doi.org/10.1002/ejoc.201800083. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.es_ES
dc.description.abstractThree new boron dipyrromethene (BODIPY) dyes substituted with a benzylamino group at the 3-position have been synthesized from halogenated BODIPYs by nucleophilic substitution. The spectroscopic and photophysical properties have been explored in different solvents and have been compared with an analogous 8benzylaminoBODIPY derivative. The position of the benzylamino group has a significant influence on the spectral band positions, fluorescence quantum yields, and fluorescence lifetimes. The 8benzylaminoBODIPY emits in the blue range, whereas the 3substituted shows green fluorescence. Additionally, the extension of the conjugation at the 5-position of 3-benzylaminoBODIPY produces a bathochromic shift of the absorption and emission spectra. The solvent effect on their spectroscopic features has been investigated using the generalized Catalán solvent scales. Quantum-chemical calculations have been performed to assess the effect of the position of the substitution on the spectroscopic properties. Finally, the BODIPY dyes have been employed as probes in fluorescence lifetime imaging of living cells, demonstrating their high potential for bioimaging.es_ES
dc.description.sponsorshipThis work has been financially supported by the National Nature Science Foundation of China (Grants Nos. 21672006) and Nature Science Foundation of Anhui Province (Grants No. 1508085J07); and grant CTQ2014-56370-R from the Spanish Ministry of Economy and Competitiveness and the European Regional Development Fund (ERDF).es_ES
dc.language.isoenges_ES
dc.publisherWiley-VCHes_ES
dc.titleSynthesis and spectroscopy of benzylamine-substituted BODIPYs for bioimaginges_ES
dc.typeinfo:eu-repo/semantics/articlees_ES
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses_ES
dc.identifier.doi10.1002/ejoc.201800083


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