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Please use this identifier to cite or link to this item: http://hdl.handle.net/10481/47562

Title: Symmetric Supercapacitor Electrodes from KOH Activation of Pristine, Carbonized, and Hydrothermally Treated Melia azedarach Stones
Authors: Moreno-Castilla, Carlos
García-Rosero, Helena
Carrasco Marín, Francisco
Issue Date: 4-Jul-2017
Abstract: Waste biomass-derived activated carbons (ACs) are promising materials for supercapacitor electrodes due to their abundance and low cost. In this study, we investigated the potential use of Melia azedarach (MA) stones to prepare ACs for supercapacitors. The ash content was considerably lower in MA stones (0.7% ash) than that found in other lignocellulosic wastes. ACs were prepared by KOH activation of pristine, carbonized, and hydrothermally-treated MA stones. The morphology, composition, surface area, porosity, and surface chemistry of the ACs were determined. Electrochemical measurements were carried out in three- and two-electrode cells, 3EC and 2EC, respectively, using 1 M H2SO4 as the electrolyte. The highest capacitance from galvanostatic charge-discharge (GCD) in 2EC ranged between 232 and 240 F·g−1 at 1 A·g−1. The maximum energy density reached was 27.4 Wh·kg−1 at a power density of 110 W·kg−1. Electrochemical impedance spectroscopy (EIS) revealed an increase in equivalent series resistance (ESR) and charge transfer resistance (RCT) with greater ash content. Electrochemical performance of MA stone-derived ACs was compared with that of other ACs described in the recent literature that were prepared from different biomass wastes and results showed that they are among the best ACs for supercapacitor applications.
Sponsorship: This work was supported by FEDER and Spanish MINECO (grant number CTQ-2013-44789-R); and Junta de Andalucía (grant numbers P12-RNM-2892, RNM172). HGR gratefully acknowledges COLCIENCIAS (Colombia) for supporting her PhD studies.
Publisher: MDPI
Keywords: Melia azedarach stones
Biomass wastes
Activated carbons
Supercapacitor electrodes
Energy storage
URI: http://hdl.handle.net/10481/47562
ISSN: 1996-1944
Citation: Moreno Castilla, C.; García Rosero, H.; Carrsco Marín, F. Symmetric Supercapacitor Electrodes from KOH Activation of Pristine, Carbonized, and Hydrothermally Treated Melia azedarach Stones. Materials, 10(7): 747 (2017). [http://hdl.handle.net/10481/47562]
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