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Please use this identifier to cite or link to this item: http://hdl.handle.net/10481/31913

Title: Bis(cyanato-[kappa]N)bis(5,7-dimethyl-1,2,4-triazolo[1,5-a]pyrimidine-[kappa]N3)zinc
Authors: Caballero Hernández, Ana Belén
Quirós Olozábal, Miguel
Rodríguez-Diéguez, Antonio
Salas Peregrín, Juan Manuel
Issue Date: 2011
Abstract: In the title complex, [Zn(NCO)2(C7H8N4)2], the ZnII ion exhibits a distorted tetrahedral coordination geometry. The coordination environment is formed by two 5,7-dimethyl-1,2,4-triazolo[1,5-a]pyrimidine (dmtp) ligands, coordinated through the N atom in position 3, and two cyanate anions interacting by their N atoms. Supramolecular dimers are generated by stacking interactions between the pyrimidine rings of two ligands related by an inversion center [centroid-centroid distance = 3.5444 (18) Å].
Sponsorship: Financial support from the Junta de Andalucia (FQM-3705 and FQM-4228) and the Spanish Ministry of Education (FPU fellowship of Ana B. Caballero) is gratefully acknowledged.
Publisher: International Union of Crystallography
Keywords: Single-crystal X-ray study
Metal-organic compounds
URI: http://hdl.handle.net/10481/31913
ISSN: 1600-5368
Citation: Caballero, A.B.; et al. Bis(cyanato-[kappa]N)bis(5,7-dimethyl-1,2,4-triazolo[1,5-a]pyrimidine-[kappa]N3)zinc. Acta Crystallographica Section E, 67(3): m345 (2011). [http://hdl.handle.net/10481/31913]
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