@misc{10481/72283,
year = {2021},
month = {11},
url = {http://hdl.handle.net/10481/72283},
abstract = {A novel Zn-based-MOF material, called Zn-URJC-8, containing two different organic linkers, 2-aminoterephtallic 
acid and 4,4-bipyridyl, has been synthetized and used for catalytic purposes for the first time. The structure of 
Zn-URJC-8 has been determined by single-crystal X-ray diffraction (XRD) showing -NH2 groups inward-facing of 
narrow pores, providing the material with excellent properties as CO2 adsorbent. The good results obtained by 
means of carbon dioxide adsorption isotherms have demonstrated the high interaction between CO2 and -NH2 
groups with a Qst value of 54 kJ/mol at low coverage. The Zn-URJC-8 material also display promising results as 
catalyst for CO2 transformation in added value products. Almost complete conversion of epichlorohydrin and 
CO2 in cycloaddition reaction has been achieved under mild conditions, and the influence of different radical 
groups coordinated to the epoxides has been evaluated on the reaction yield. The recyclability has been also 
tested and the structural integrity of the catalyst is maintained after several consecutive reaction cycles.},
organization = {Regional Government of Madrid

ACES2030-CM, S2018/EMT-4319},
organization = {Ministerio de Ciencia e Innovación},
organization = {Agencia Estatal de Investigación

	PGC2018-099296-B-I00},
publisher = {Elsevier},
keywords = {CO2 conversion},
keywords = {Zn-based-MOF},
keywords = {CO2 adsorption},
keywords = {Cycloaddition reaction},
keywords = {Epoxides},
keywords = {Recyclability},
title = {A novel Zn-based-MOF for efficient CO2 adsorption and conversion under mild conditions},
doi = {10.1016/j.cattod.2021.11.025},
author = {Orcajo, Gisela and Rodríguez Diéguez, Antonio and Choquesillo Lazarte, Duane},
}